There’s not a huge amount of information online about life in Bolivia but there are a few good sites out there. Check out my recommendations.
Boliviabella is by far the most comprehensive English language source of information about Bolivia on the internet. The focus is on Santa Cruz but there’s heaps of info about all aspects of the country.
Bolivia in my eyes is an interesting blog from a Polish expat living in Santa Cruz. Scroll down to get to the English section of each post.
Bolivian Thoughts has a wealth of information although some it is seems to have been put through Google translator so readability can be an issue.
Strolling South America has numerous interesting posts about life in La Paz from a former expat who has now moved on in her travels.
There is also an “Expats Bolivia” group on Facebook that’s worth a look.